By Dr. Glenn T. Seaborg (auth.), Norman M. Edelstein, James D. Navratil, Wallace W. Schulz (eds.)
The papers integrated during this quantity have been offered on the symposium on "Americium and Curium Chemistry and expertise" on the foreign Chemical Congress of Pacific Basin Societies in Honolulu, Hawaii, December 16-21, 1984. This symposium honored 40 years of analysis on americium and curium. for this reason, the papers incorporated during this quantity commence with historic views at the discovery of americium and curium and the early characterization in their chemical homes, after which hide quite a lot of matters, reminiscent of thermodynamic homes, digital constitution, nuclear reactions, analytic chemistry, excessive strain part transitions, and technological features. hence, this quantity is a overview of the chemistry of americium and curium, and gives a standpoint at the present examine on those components 40 years after their discovery. The editors want to thank the members during this symposium for his or her contributions. it's a excitement to recognize the help of Ms. Barbara Moriguchi in dealing with the executive elements of the symposium and of the construction of this quantity. April 2, 1985 Norman M. Edelstein fabrics and Molecular examine department Lawrence Berkeley Laboratory collage of California Berkeley, California 94720, U.S.A. James D. Navratil Rockwell overseas Rocky apartments Plant P.O. field 464 Golden, Colorado 80402-0464, U.S.A. Wallace W. Schulz Rockwell Hanford P.O. field 800 Richland, Washington 99352, U.S.A.
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Extra info for Americium and Curium Chemistry and Technology: Papers from a Symposium given at the 1984 International Chemical Congress of Pacific Basin Societies, Honolulu, HI, December 16–27, 1984
1967, ~§, No. 32, 74. ~b~m~ ~Dg gDg~ ~~~~~ 28. K. , "Lanthanide/Actinide Chemistry," Amer. Chem. , 248. 20 YEARS OF AMERICIUM AND CURIUM RESEARCH AT THE EUROPEAN INSTITUTE FOR TRANSURANIUM ELEMENTS W. Muller Commission of the European Communities, Joint Research Centre Karlsruhe Establishment European Institute for Transuranium Elements Postfach 2266 D-7500 Karlsruhe Federal Republic of Germany ABSTRACT. Part of the European Institute for Transuranium Elements' research programme which is aimed at elucidating the role of 5f electrons in the chemical bond has been devoted to the study of americium and curium.
M. Edelstein et al. ), Americium and Curium Chemistry and Technology, 43-49. © 1985 by D. Reidel Publishing Company. 44 O. L. KELLER Jr. would be fairly readily oxidizable to the VI state to ions analogous to PuO~+ The experiments based on this assumption did not bear fruit, and it became apparent that some new tack had to be taken. There were also, of course, various assumptions about the untried nuclear reactions that were used in these unsuccessful attempts to produce Am and Cm from the 239pu target.
The diluent nature oonsiderably affects americium and ourium isolation, but has praotically no effeot on the rare earths. Beta-Diketones have also been used for amerioium and ourium isolation and their following determination. 1-phenyl-)-methyl-4-benzoyl-pyrazolone-5 (PMBP) is the most thoroughly studied example in the works of the soviet authors (66). It extraots a number of elements, inoluding ourium (67) from more aoid media than thenoyltrifluoroaoetone (TTA). The presenoe of salts greatly influenoes amerioium extraotion by this reagent (68).