A critical review of the 2002 fiterature preceded by three by Gordon W. Gribble and John A. Joule (Eds.)

By Gordon W. Gribble and John A. Joule (Eds.)

This can be the 15th annual quantity of development in Heterocyclic Chemistry, which covers the literature released in the course of 2002. the quantity opens with 3 stories on present heterocyclic subject matters. The spotlight chapters in quantity 15 are all written through prime researchers of their box and those chapters represent a scientific survey of the $64000 unique fabric pronounced within the literature on heterocyclic chemistry in 2002. As with prior volumes within the sequence, quantity 15 will allow the reader to maintain abreast of advancements in heterocyclic chemistry in a simple way.A severe assessment of the heterocyclic literature released in the course of 2002.Opens with 3 really good reports on new constructing themes of curiosity to heterocyclic chemists. next chapters evaluate advances within the formation and response of heterocyclic rings.Chapters all written via major researchers of their box.

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B. J. Danishefsky, J. Am. Chem. Soc. 2002, 124, 9825 X. R. R. H. Hoveyda, J. Am. Chem. Soc. E. A. F. L. Snapper, J. Am. Chem. Soc. G. S. J. A. Hilfiker, J. Am. Chem. Soc. 2002, 124, 13654 P. R. Rector, H. Takahashi, J. Am. Chem. Soc. A. Waiters, F. La, P. O. Omecinsky, J. Comb. Chem. A. Hunt, P. J. Moody, J. Chem. , Perkin Trans. 1 2002, 2378 J. Cossy, C. Willis, V. Bellosta, S. BouzBouz, J. Org. Chem. 2002, 67, 1982 M. Sasaki, T. Noguchi, K. Tachibana, J. Org. Chem. 2002, 67, 3301 N. Buschmann, A.

2002, 4, 3875 A. Rivkin, K. -C. J. Danishefsky, Org. Lett. 2002, 4, 4081 P. Van de Weghe, D. G. Boiteau, J. Eustache, Org. Lett. E. K. Kim, B. Ledoussal, Org. Lett. 2002, 4, 4499 M. Inoue, H. Uehara, M. Maruyama, M. Hirama, Org. Lett. D. T. R. Hanson, Org. Lett. 2002, 4, 4673 A. R. W. T. D. R. Hanson, Phosphorus, Sulfur Silicon Relat. Elem. S. R. Hanson, Phosphorus, Sulfur Silicon Relat. Elem. B. Lindsay, M. G. G. Davies, K. P. D. Smith, H. Rodriguez-Solla, Synlett 2002, 1146 T. Bach, A. Lemarchand, Synlett 2002, 1302 K.

These results are entirely consistent with the electrocyclic ring closure - heteroatom migration mechanism shown in Scheme 31 <94JA2292>. Photochemical Isomerizations of Some Five-Membered Heteroaromatic Azoles ~_~ Ph S 51 2 3 --I~sN Ph 4 hv 53 BC-53 Scheme29 ~ N Ph S hv D Ph Ph D ~S ~ Ph + D~s~N 53-4d 55-5d 53-2d D + 55-3d Scheme30 ll s --N D D BC-53-2d BC-55-5d hv S 53-2d D hv D hv Ph Ph BC-55-3d Ph D S Ph~D BC-53-4d hv D Ph 55-5d 55-3d S 53-4d Scheme31 These results reveal that both 1-methylpyrazoles and phenylthiazoles and isothiazoles phototranspose by the electrocyclic ring closure - heteroatom migration mechanistic pathway.

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